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Paleosols (fossil soils) are preserved throughout the geologic record in depositional settings ranging from alluvial systems to between basalt flows. Until recently, paleosols were studied using primarily qualitative methods. In recent years, paleopedology has shifted from a largely qualitative field based on comparisons with modern analogues to an increasingly quantitative endeavor. Some of this change has been a result of applying existing techniques to new materials, but many of the innovations have been the result of applying new techniques to new materials, including thermodynamic modeling of soil formation, isotope geochemistry, and applications of empirical relationships derived from modern soils. A variety of semi-quantitative and quantitative tools has been developed to examine past weathering and pedogenesis, and to reconstruct both paleoenvironmental and paleoclimatic conditions at the time that the paleosols formed. Though it is often not possible to achieve the same temporal resolution as with marine records for paleoclimatic reconstructions, proxies based on paleosols are potentially a much more direct means of making paleoclimatic reconstructions because soils form at the Earth's surface, in direct contact with the atmospheric and climatic conditions at the time of their formation. Paleoclimatic and environmental properties that may be reconstructed using the new proxies include provenance, weathering intensity, mean annual precipitation and temperature during pedogenesis, nutrient fluxes into and out of the paleosols, the atmospheric composition of important gases including CO2 and O2, the moisture balance during pedogenesis, the soil gas composition, reconstructed vegetative covering, and paleo-altitude.